Currently it is not possible to determine which Team record belongs to each Solution in Jira Align. In the UI, if you go to the Teams grid and look for teams of Type = Solution Team you can see the information but this is not possible to identify in Enterprise Insights.

In the attached screenshots there is an example where we see different values for the IDs in Jira Align in the left panel and in the details panel.

In Enterprise Insights we have one of the IDs in the Team table and the other on the Solution table. There is no FK to have the relationship between Teams and Solutions.